Trends in Polyoxometalates Research

Laurent Ruhlmann (Editor)
University of Strasbourg, Strasbourg Cedex, France

Delphine Schaming (Editor)
University Paris Diderot, Paris, France

Series: Chemistry Research and Applications
BISAC: SCI013000




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The book attempts to make available the recent developments in polyoxometalate (POM) synthesis. The focus centralizes on the functionalization of POMs with covalently organic moiety (for instance, the use of exogenous ligands such as carboxylate or bisphosphonate). It also delves into the development of lanthanide POMs, or the formation of blackberry-like assemblies. Likewise, the properties (redox properties, magnetism, etc…), and its applications (homogeneous and heterogeneous catalysis, photocatalysis, photoelectrocatalysis and photovoltaic cell development, etc.) are also analyzed.

This application concerns also the catalysis of H2O oxidation, photodegradation of pollutants, and reduction of cationic metal to form original nanoparticles. The use of polyoxometalates as catalysts for biologically relevant reactions is also considered. One of the other aims of the book is to highlight some recent developments and perspectives in the domain of materials and their applications. For instance, the use of POM-organic photosensitizer hybrids can also be achieved for application in the generation of photocurrent and the development of new types of solar cells. By combining POMs with electrically active materials, a variety of applications have been explored and several examples of POM-based electronic materials are presented in this book.
(Imprint: Nova)


Controllable Self-Assembly Process of Polyoxometalate Macroions Driven by Counterion Mediated Attraction
(Fadi Haso, Baofang Zhang, Jing Zhou,and Tianbo Liu, Department of Polymer Science, The University of Akron, Akron, OH, USA)

Building New Polyoxotungstates using Exogeneous Ligands: From Carboxylato to Bisphosphonato Complexes
(Olivier Oms, Pierre Mialane and Anne Dolbecq, Institut Lavoisier de Versailles, Université de Versailles Saint-Quentin, Versailles Cedex, France)

POM-Based Chiral Hybrids via Organically Covalent Modification of Achiral Precursors
(Jiangwei Zhang, Yichao Huang and Yongge Wei, Department of Chemistry, Tsinghua University, Beijing, P. R. China)

POM Complexes with Noble Metals – New Insights into Synthesis and Reactivity
(Sokolov M. N., Adonin S. A., Vicent C., Nikolaev Institute of Inorganic Chemistry, Novosibirsk, Russia, and others)

Synthesis and Characterization of Lanthanoid Containing Polyoxotungstates Nanocluster
(Rakesh Gupta and Firasat Hussain, Department of Chemistry University of Delhi, Delhi)

Polyoxometalate-based Single-Molecule Magnets
(Natalya V. Izarova, Paul Kögerler, Peter Grünberg Institute, Forschungszentrum Jülich, Jülich, Germany, and others)

Small Angle X-ray Scattering of Group V Polyoxometalates
(May Nyman and Lauren Fullmer, Department of Chemistry, Oregon State University, Corvallis, Oregon, USA)

Polyoxometalate Reactivity toward Biomolecules and their Model Systems
(Stroobants Karen, Absillis Gregory and Parac-Vogt Tatjana N., Laboratory of Bioinorganic Chemistry, Department of Chemistry, KU Leuven, Belgium)

Polyoxometalate-Containing Hybrid Diblock Copolymers: Synthesis, Morphology, and Applications
(Ruixin Wang, Sanjiban Chakraborty, Yong Li, and Zhonghua Peng, Departmentof Chemistry, University of Missouri-Kansas City, Kansas City, MO, USA, and others)

Polyoxometalates Associated with Porphyrins used as Efficient Visible Photosensitizers
(Delphine Schaming and Laurent Ruhlmann, Laboratoire « Interfaces, Traitements, Organisation et DYnamique des Systèmes » CNRS/Université Paris Diderot (Sorbone Paris Cité), France, and others)

Development of Polyoxometalate-Based Material Photocatalysts for Organic Dye Degradation under Visible Light
(Shui-Ying Gao, Jian Lü and Rong Cao, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, P. R. China)

Polyoxometalate-Containing Multifunctional Materials
(Solomon Omwoma, Wei Chen, Christopher T. Gore, Yu-Fei Song, State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, P. R. China)

POM-based Molecular and Composite Materials toward Electronic Applications
(Ryo Tsunashima, Graduate School of Science and Engineering, Yamaguchi University, Yoshida, Yamaguchi, Japan)

Porous Materials Containing Polyoxometalates and their Applications in Catalysis
(LaSalle Swenson, Jose C. Orozco and M. Ishaque Khan, Department of Biological and Chemical Sciences, Illinois Institute of Technology, Chicago, IL, USA)

Assembly of Epsilon-Keggin-Type Polyoxometalates to form Crystalline Microporous Metal Oxides
(Zhenxin Zhang, Masahiro Sadakane, and Wataru Ueda, Catalysis Research Center, Hokkaido University, Kita-ku, Sapporo, Japan, and others)


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