Supramolecular Systems: Chemistry, Types and Applications

Charlotte Pena (Editor)

Series: Chemistry Research and Applications
BISAC: SCI013000

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Supramolecular chemistry provides ingenious strategies for the elaboration of functional systems from readily available molecular components. These methodologies have been used for the development of sensors, catalysts, energy or electron transfer systems, agents for photodynamic therapy and so forth. This book reviews the chemistry, types and applications of supramolecular systems. Chapter One discusses the design and applications of supramolecular systems based on (thia)calixarene ammonium derivatives. Chapter Two gives an overview of the methods of stabilization of the elusive bare {V6O19} structure by different capping moieties and substituents, illustrates the main synthetic strategies toward the formation of fully-oxidized {VV6}, mixed-valence {VV/IV6}, and “fully-reduced” {VIV6} trisalkoxohexavanadates, describes bis-(trisalkoxo)hexavanadates obtained by post-functionalization reactions, and details their reactivity toward transition metals and lanthanoid complexes. Chapter Three emphasizes the suitability of supramolecular interactions to provide porous materials which have been called Supramolecular Metal-Organic Frameworks (SMOFs). Chapter Four discusses self-assembly of porphyrins in the context of its relevance to photosynthesis. (Imprint: Nova)

Preface

Chapter 1. Design and Applications of Supramolecular Systems Based on (THIA)Calixarene Ammonium Derivatives
Ivan I. Stoikov, Pavel L. Padnya, Elena A. Andreyko, and Joshua B. Puplampu (Organic Chemistry Department, A.M. Butlerov Chemical Institute, Kazan Federal University, Kazan, Russian Federation, and others)

Chapter 2. The Lindqvist Hexavanadate: A Platform for Coordination-Directed Assembly
Oliver Linnenberg, Aleksandar Kondinski and Kirill Yu. Monakhov (Institute of Inorganic Chemistry, RWTH Aachen University, Aachen, Germany)

Chapter 3. Supramolecular Metal-Organic Frameworks based on Metal-Nucleobase Entities
Sonia Pérez-Yáñez, Garikoitz Beobide, Oscar Castillo, Javier Cepeda and Antonio Luque (Departamento de Química Inorgaìnica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, UPV/EHU, Apartado, Bilbao, Spain)

Chapter 4. Biomimetic Studies of Porphyrin Self-Assembled Systems
A. G. Bessmertnykh-Lemeune, R. Guilard, C. Stern, Yu. Yu. Enakieva, Yu. G. Gorbunova, A. Yu. Tsivadze, S. E. Nefedov (Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB), Dijon, France, and others)

Index

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