Quantitative Chemistry, Biochemistry and Biology: Steps Ahead

Gennady E. Zaikov (Editor)
Head of Polymer Division, N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia

Oleg V. Stoyanov (Editor)
Kazan National Research Technological University, Kazan, Russia

Wiktor Tyszkiewicz (Editor)
Military Institute of Chemistry and Radiometry, Warsaw, Poland

Zbigniew Wertejuk (Editor)
Military Institute of Chemistry and Radiometry, Warsaw, Poland

Series: Chemistry Research and Applications, Biochemistry Research Trends
BISAC: SCI013000

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The monk Jesuit Escober proposed the slogan “The aim justifies the means”. This slogan at large is not correct because it permits any action. However in this particular case, this slogan is acceptable because the aim is to target the reader.

Reviews and original papers were collected about quantitative chemistry, biochemistry and biology. Special attention is given to new ideas in the fields which include nanoelements formation and reactivity, synthesis of thermoplastic bio-based polyurethanes on the basis of vegetable oils, carvacrol and thymol for fresh food packaging, polymer composites structure and electric properties and some properties of small water clusters in water-starch systems.

The following topics are also discussed: investigation of kinetics and mechanism of biologically awake antioxidants in reaction to esterification 2- (n-acetylamid)-3-(3′, 5′-di-tert.butyl-4 ‘-hydroxyphenyl)-propionic acid, the turbulent apparatus for oil neutralization, еffect melaphen on a mitochondria of sprouts of peas under stressful influences by some methods, preparation of new antioxidants in reaction 2- (n-methylamide)-3- (3 ‘, 5 ‘-di-tert.butyl-4 ‘-hydroxyphenyl)-propionic acid and effect of external influences on the structural and dynamic parameters of polyhydroxybutyrate-hydroxyvalerate-based biocomposites.

Also mentioned include the problems of determination diffusion coefficients of Brownian particles using velocity or force autocorrelation function in molecular dynamic simulations, in silico simulation of silver and copper ions interacting with fungal cell wall in vitro antifungal activity of copper ions and silver ions) and the estimation of antioxidants as nuts quality index and the structure of soluble unlinked and cross-linked fibrin oligomers. (Imprint: Nova)

Preface

Chapter 1. New Ideas in the Field of Nanoelements Formation and Reactivity
(A.M. Lipanov and A.V. Vakhrushev, Institute of Mechanics, Ural Branch of the Russian Academy of Sciences, Izhevsk, Russia)

Chapter 2. Synthesis of Thermoplastic Bio-Based Polyurethanes on the Base of Vegetable Oils
(C. Bueno-Ferrer, N. Burgos and A. Jiménez, Analytical Chemistry, Nutrition & Food Sciences Department, University of Alicante, Alicante, Spain)

Chapter 3. Carvacrol and Thymol for Fresh Food Packaging
(Marina Ramos, Ana Beltrán, Arancha Valdés, Mercedes A. Peltzer, Alfonso Jiménez and María C. Garrigós, Analytical Chemistry, Nutrition & Food Sciences Department, University of Alicante, Alicante, Spain)

Chapter 4. Some Properties of Small Water Clusters in Water-Starch Systems
(N.A. Grunina, G.I. Tsereteli, T.V. Belopolskaya, O.I. Smirnova and L.O. Rodriguez Castillo, Institute for Physics of Physical Department of St.Petersburg State University, Russia)

Chapter 5. Solubility of Aluminum Polyhydroxochloride in the Water-Acetone Solution
(V.F. Kablov, N.U. Bykadorov, O.K. Zhokhova, M.P. Spiridonova and D.A. Provotorova, Volzhsky Polytechnical Institute, Branch of Federal State Budgetary Educational Institution of Higher Professional Education, Volgograd State Technical University, Volgograd Region, Russia)

Chapter 6. Diversified Fenomena of Entropy
(G.А. Korablev, N.G. Petrova, R.G. Korablev, A.K. Osipov and G.E. Zaikov, Izhevsk State Agricultural Academy, Russia, and others)

Chapter 7. Quantitative Calculation of Spatial-Energy Interactions Entropy
(G.А. Korablev, N.G. Petrova, R.G. Korablev and G.E. Zaikov, Izhevsk State Agricultural Academy, Russia, and others)

Chapter 8. Bacterial Plasmids: Cloning of Multi-Copy CpG Motifs
(A.S. Korovashkina, S.V. Kvach and A.I. Zinchenko, Institute of Microbiology, National Academy of Sciences, Minsk, Belarus)

Chapter 9. Using Full-Length Diguanylate Cyclase of Thermotoga Maritime for Enzymatic Synthesis of 3′,5′-Cyclic Diguanylate
(A.S. Korovashkina, S.V. Kvach, M.V. Kvach, A.N. Rymko and А.I. Zinchenko, Institute of Microbiology, National Academy of Sciences, Minsk, Belarus)

Chapter 10. The Segmental and Translational Movements of Polystyrene into Solutions: Investigation of Kinetic Parameters
(Yuriy Medvedevskikh and Oksana Khavunko, Physical Chemistry of Combustible Minerals Department, Institute of Physical–Organic Chemistry & Coal Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine, Lviv, Ukraine)

Chapter 11. Interaction of Hydroxy Organocyclotetrasiloxanes with Propyl Butyrate Side Groups and Polymer Electrolyte Membranes on their Basis: Ring Opening Polymerization Reactions
(T. Tatrishvili, E. Markarashvili, I. Esartia, J. Aneli, G.E. Zaikov and O. Mukbaniani, Iv. Javakhishvili Tbilisi State University, Tbilisi, Georgia, and others)

Chapter 12. UV-Protective Properties of Nanocomposites Films Based on Low Density Polyethylene
(A.A. Olkhov, S.V. Romanov, A.A. Ischenko and G.E. Zaikov, Moscow M.V. Lomonosov State University of Fine Chemical Technology, Moscow, Russia, and others)

Chapter 13. Biodegradable Compositions of Starch with Synthetic Polymers and Natural Polysaccharides: Production, Morphology and Properties
(S.Z. Rogovina, K.V. Aleksanyan and E.V. Prut, Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia)

Chapter 14. Kinetics and Mechanism of the Chemically Modificated Starches during Gelatinization
(A.I. Sergeev, N.G. Shilkina, L.A. Wasserman and H. Staroszczyk, Institute of Chemical Physics RAS, Moscow, Russia, and others)

Chapter 15. Investigation of Ethylene Copolymers Silanol Modification
(S.N. Rusanova, O.V. Stoyanov, A.B. Remizov, A.O. Yanaeva, V.K. Gerasimov, A.E. Chalykh and G.E. Zaikov, Department of Plastics Technology, Kazan State Technological University, Russia, and others)

Chapter 16. Determining the Surface Free Energy Parameters
(A. Starostina, O.V. Stoyanov, N.V. Makhrova, G.E. Zaikov and R. Ya. Deberdeev, Kazan National Research Technological University, Kazan, Tatarstan, Russia, and others)

Chapter 17. Investigation of Ethylene–Vinylacetate Copolymers Binary Mixtures Structure
(O.V. Stoyanov, R.M. Khuzakhanov, L.F. Stoyanova, V.K. Gerasimov, A.E. Chalykh, A.D. Aliev, M.V. Vokal and G.E. Zaikov, Kazan State Technological University, Kazan, Republic of Tatarstan, Russia, and others)

Chapter 18. Еffect of Melaphen on a Mitochondria of Sprouts of Peas under Stressful Influences by the AFM Method
(V.I. Binyukov, E.M. Mil, I.V. Zhigacheva, A.A. Albantova, I.P. Generozova and A.G. Shugaev, N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia, and others)

Chapter 19. Effect of External Influences on the Structural and Dynamic Parameters of Polyhydroxybutyrate–Hydroxyvalerate-Based Biocomposites
(S.G. Karpova, A.L. Iordanskii, A.A. Popov, N.G. Shilkina, S.M. Lomakin, M.A. Shcherbinа, S.N. Chvalun and A.A. Berlin, N.M. Emmanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia, and others)

Chapter 20. Composite Materials Based on LDPE with the Addition of Wood Flour and Rubbers of Different Nature
(A.V. Koroleva, Yu. K. Lukanina, A.V. Khvatov, N.N. Kolesnikova, P.V. Pantiukhov, A.A. Olkhov and A.A. Popov, Federal State Institution of Science, N.M. Emanuel Institute of Biochemical Physics, Moscow, Russia, and others)

Chapter 21. Fungicidal Influence of Ions of Сu2+ on Microorganisms as a Way of Biocorrosion Protection of Metal Constructions
(Yu. K. Lukanina, N.N. Kolesnikova, A.V. Khvatov, А.N. Likhachev and А.А. Popov, N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Science, Moscow, Russia, and others)

Chapter 22. Interfacial Rheology of Hen Egg White Lysozyme-5-Methylresorcinol Mixtures and their Foaming Properties
(E.I. Martirosova and I.G. Plashchina, N.M. Emanuel Institute of Biochemical Physics RAS, Moscow, Russia)

Chapter 23. Structure and Thermophysical Properties of Blends Based on Isotactic Polypropylene and Low-Density Polyethylene
(E.E. Mastalygina, S.G. Karpova, N.N. Kolesnikova, U.K. Lukanina and A.A. Popov, Department of Biological and Chemical Physics of Polymers, N.M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, Moscow, Russia, and others)

Chapter 24. Investigating the Effect of Fungi on Thin Films of Polyethylene, Polyethylene–Poly-3-Hydroxybutyrate and
Polyethylene–d2w
(Yu. V Tertyshnaya, S. Dempsey and A.A. Popov, N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia, and others)

Chapter 25. Determination of the Identity of the Signs of Natural Pomegranate Juice
(E.A. Barishovets and L.G. Eliseeva, Plekhanov Russian University of Economics, Russian Federation, Moscow, Russia)

Chapter 26. Influence of Carbon Nanofibers on the Structure and Properties of Vulcanized EPDM
(M.M. Ryabenko, V.D. Yulovskaya and B.V. Peshnev, Moscow State University of Fine Chemical Technology, Russia)

Chapter 27. Determination Diffusion Coefficient of Brownian Particles Using Velocity or Force Autocorrelation Function in Molecular Dynamic Simulations
(D.A. Turchenkov, BioSim Research Group, Moscow, Russia)

Chapter 28. In Silico Simulation of Silver and Copper Ions Interacting with Fungal Cell Wall: In Vitro Antifungal Activity of Copper Ions and Silver Ions
(M.A. Turchenkov, BioSim Research Group, Moscow, Russia)

Chapter 29. The Estimation of Antioxidants as Nuts Quality Index
(O.V. Yurina and L.G. Eliseeva, Plekhanov Russian University of Economics, Moscow, Russia)

Chapter 30. Structure of Soluble Unlinked and Cross-Linked Fibrin Oligomers
(M.A. Rosenfeld, V.B. Leonova, M.I. Biryukova, E.A. Kostanova and M.V. Vasileva, N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia)

Chapter 31. Kinetics and Mechanism of the Ozone Reaction with Alcohols, Ketones, Ethers and Hydroxybenzenes
(Slavcho Kirillov Rakovsky, Metody Anachkov, Mikhail M. Belitskii and G.E. Zaikov, Institute of Catalysis, Bulgarian Academy of Sciences, Sofia, Bulgaria, and others)

Chapter 32. The Mechanism of the Selective Ethylbenzene Oxidation Catalyzed with Triple Binuclear Metallocomplex Catalysts, Including Ni and Redox-Inactive Metal Na (or Li): Nanostructures {NiII (acac)2•NaSt (or LiSt)•(PhOH)}n Formation due to Intermolecular H-Bonds
(L.I. Matienko, V.I. Binyukov, L.A. Mosolova and G.E. Zaikov, N M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia)

Chapter 33. Effect of the Stereometry on the Reactivity of Terpenephenols and their Phenoxyl Radicals in the Initiated Oxidation Reactions
(L.I. Mazaletskaya, N.I. Sheludchenko, L.B. Dudnik and L.N. Shishkina, N.M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, Moscow, Russia)

Index

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