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Barbara Pabin–Szafko
West Pomeranian University of Technology, Szczecin, Poland
Series: Chemical Engineering Methods and Technology
BISAC: TEC009010
Functional initiators find application in conventional radical polymerization for the synthesis of polymers with higher molecular weights, oligomers and block or graft copolymers. The initiator functionality can be considered by reason of the presence of functional end groups, such as hydroxyl and carboxyl, or azo and perester bonds, which undergo dissociation to the alkyl, alkoxy or acyloxy radicals under the influence of temperature or irradiation. This book examines how functional initiators were used for synthesis of ditelechelic oligomers/polymers and “active” polymers with perester groups that possess the character of macromolecular initiators. (Imprint: Nova)
Table of Contents
ABSTRACT
INTRODUCTION
SYNTHESIS OF AZOESTERS
SYNTHESIS OF AZO-ACID AND ITS DERIVATIVES
FUNCTIONAL AZO-INITIATORS IN RADICAL POLYMERIZATION
POTENTIAL POSSIBILITIES FOR AZOINITIATORS APPLICATION
CONCLUSION
REFERENCES
INDEX
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