Novel Applications of Terbium by using Flow-Through Luminescence Sensors

A. Ruiz-Medina (Editor)
E. J. Llorent-Martínez (Editor)
Department of Physical and Analytical Chemistry, Faculty of Experimental Sciences, University of Jaén, Campus Las Lagunillas, Jaén, Spain

Series: Chemistry Research and Applications
BISAC: SCI013000

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Volume 10

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Volume 2

Volume 3

Special issue: Resilience in breaking the cycle of children’s environmental health disparities
Edited by I Leslie Rubin, Robert J Geller, Abby Mutic, Benjamin A Gitterman, Nathan Mutic, Wayne Garfinkel, Claire D Coles, Kurt Martinuzzi, and Joav Merrick

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Terbium (III) ion can form stable coordination complexes or chelates with a variety of organic ligands, exhibiting high stability and strong luminescence. In these complexes, the energy absorbed by the organic chromophore at its characteristic excitation wavelength is transferred to a triplet state of the molecule and then intramolecularly transferred to a resonance level of the terbium ion, which finally emits luminescence. The main features of this process are a large Stokes shift, a narrow-band emission (specific of the terbium ion) and a long luminescence lifetime. This book reviews the characteristics of the TSL process and particular attention is paid to the development of TSL optosensors, due to their potential applications in a wide range of fields. (Imprint: Nova)

ABSTRACT

1. INTRODUCTION

2. ENERGY TRANSFER PROCESS

3. TERBIUM-SENSITIZED LUMINESCENCE PROPERTIES

4. SOLID-PHASE SPECTROSCOPY

5. TSL OPTOSENSORS

6. TSL FLOW-THROUGH OPTOSENSING: MANIFOLDS AND APPLICATIONS

CONCLUSION

REFERENCES

INDEX

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