Iron (III) Phosphate: Production and Their Uses in Organic Synthesis

$230.00

Series: Chemistry Research and Applications
BISAC: SCI013040

This book presents the synthesis, properties, uses, structure, and safety of iron (III) phosphate, as well as its use as an intercalation electrode in lithium-ion batteries, despite having low electronic conductivity. In the synthesis of organic compounds, iron (III) phosphate catalyzes the one-pot synthesis of dihydropyrimidinones and thiones, and 2, 4, 5–triarylated imidazoles. It also results in the acetylation of alcohols and phenols, the tetrahydropyranylation and tetrahydrofuranylation of alcohols and phenols, as well as the synthesis of polyhydroquinoline derivatives, 2-substituted benzimidazoles, 1, 2-disubstituted benzimidazoles, 1,2,4,5-tetra-arylated imidazoles, and bis(indolyl)methanes.

Furthermore, it catalyzes the one pot three-component mannich reaction, 2-substituted imidazolines, ß-amido carbonyl compounds, 1,4-dihydropyridines, 4,4’-diaminotriaryl methanes-leucomalachite materials, N-substituted pyrroles, 7,10,11,12-tetrahydrobenzo[c] acridin-8(9h)-ones, and 4,6-disubstituted 2-aminopyridine-3-carbonitriles. It results in the one-pot synthesis of octahydroquinazolinones, the conversion of tetrahydropyranyl ethers to acetates, dihydropyrimidinones, thiones, as well as β-amino ketones. In the author’s opinion, this book could be beneficial for researchers, graduates, and post graduate students, as well as for professionals in the chemical and medicinal industries in the preparation of raw materials using green methods.
(Imprint: Nova)

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Table of Contents

Table of Contents

Preface

Chapter 1. Properties, Production and Uses of Iron (III) Phosphate
(Farahnaz K. Behbahani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 2. FePO4–Catalyzed One-Pot Synthesis of Dihydropyrimidinones and Thiones
(Majid M. Heravi, Farahnaz K. Behbahani, V. Zadsirjan and Hossien A. Oskooie, Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran)

Chapter 3. One-Pot Three Component Synthesis of 2, 4, 5–Triarylated Imidazoles Using FePO4
(Farahnaz K. Behbahani, Talaye Yektanezhad and Afshin R. Khorrami, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 4. Acetylation of Alcohols and Phenols Promoted Using Iron (III) Phosphate
(F. K. Behbahani, M. Farahani and H. A. Oskooie, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran, and others)

Chapter 5. The Tetrahydropyranylation and Tetrahydrofuranylation of Alcohols and Phenols Catalyzed by FePO4 as a Cost-Effective and Recyclable Catalyst
(Farahnaz K. Behbahani and Mona Farahani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 6. Iron (III) Phosphate-Catalyed Synthesis of Polyhydroquinoline Derivatives through the Hanthzsch Four Component
(Farahnaz K. Behbahani and Maryam Homafar, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 7. One-Pot Synthesis of 2-Substituted Benzimidazoles Using Anhydrous FePO4
(Farahnaz K. Behbahani and Parisa Ziaei, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 8. Iron (III) Phosphate as a Catalyst for the One-Pot Synthesis of 1, 2-Disubstituted Benzimidazoles
(Farahnaz K. Behbahani and Parisa Ziaei, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 9. The One-Pot Synthesis of 1,2,4,5-Tetra-Arylated Imidazoles in a Greener Route Using Iron (III) Phosphate
(Farahnaz K. Behbahani and Talayeh Yektanezhad, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 10. Iron (III) Phosphate-Catalyzed Synthesis of Bis(Indolyl)Methanes
(Farahnaz K. Behbahani and Masoumeh Sasani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 11. FePO4-Promoted Three-Component Mannich Reaction
(Farahnaz K. Behbahani and Leili Mohammadi Ziarani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 12. Iron (III) Phosphate-Catalyzed and Water Mediated Synthesis of 2-Substituted Imidazolines
(Farahnaz K. Behbahani and Toktam Sheibani Daloee and Parisa Ziaei, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 13. The Application of FePO4 for the Synthesis of ß-Amido Carbonyl Compounds
(Farahnaz K. Behbahani, Sara Naeini and Saeed Suzangarzadeh, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran, and others)

Chapter 14. The Synthesis of Unprecedented 1,4-Dihydropyridines Using Iron(III) Phosphate
(Farahnaz K. Behbahani and Banafsheh Yazdanparast, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran

Chapter 15. Synthesis of 4,4’-Diaminotriaryl Methanes-Leucomalachite Materials in Presence of FePO4 under Solvent-Free Condition
(Farahnaz K. Behbahani and Elham Khademloo, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 16. Iron (III) Phosphate-Catalyzed Synthesis of N-Substituted Pyrroles
(Marjan Samadi and Farahnaz K. Behbahani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 17. The Preparation of 7,10,11,12-Tetrahydrobenzo[C] Acridin-8(9H)-Ones Using FePO4
(Farahnaz K. Behbahani and Mona Farahani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 18. The Synthesis of 4,6-Disubstituted 2-Aminopyridine-3-Carbonitriles Catalyzed by Iron(III) Phosphate as a Green and Reusable Catalyst
(Mahbobeh Zadpour and Farahnaz K. Behbahani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 19. One-Pot Synthesis of Octahydroquinazolinones Using Iron(III) Phosphate
(Farahnaz K. Behbahani and Hajar Biklarian, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 20. Conversion of Tetrahydropyranyl Ethers to Acetates Using FePO4
(Farahnaz K. Behbahani and Mona Farahani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 21. The Use of FePO4 in the Synthesis of Dihydropyrimidinones and Thiones
(Farahnaz K. Behbahani and Mona Farahani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Chapter 22. Click Reaction for the Synthesis of β-Amino Ketones Using FePO4
(Farahnaz K. Behbahani and Negin Bastani, Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran)

Index

Additional Information

Keywords: Iron (III) Phosphate, Organic Synthesis

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