V. S. Tkach, D. S. Suslov and G. Myagmarsuren
Irkutsk State University, Irkutsk, Russia

Series: Materials Science and Technologies
BISAC: TEC021000

Pd(β-diketonate)2/BF3∙OEt2 catalytic systems in “phosphine-free” and “phosphine-modified” fashions have been tested in the position isomerization of 1-hexene, dimerization of propylene, dimerization of styrene, telomerization of butadiene with diethylamine, addition polymerization of norbornene and its derivatives. For such systems exemplified by Pd(acac)2/BF3∙OEt2 and Pd(acac)2/PR3/BF3∙OEt2 general principles of the two-stage route of H(L)2-nPd(L’)nBF4 active sites formation are formulated, where L — unsaturated hydrocarbon, L’ — PR3 (R=Ph, n-Bu),n=0, 1, 2. This book presents an investigation into the application of BF3•OEt2 as multifunctional component of active in the transformation of unsaturated hydrocarbons Pd(II)- and Ni(0, I, II)-based catalyst systems. (Imprint: Novinka)