Application of BF3 OET2 as Multifunctional Component of Active in the Transformation of Unsaturated Hydrocarbons PD (II) and NI (0, I, II) based Catalytic Systems

V. S. Tkach, D. S. Suslov and G. Myagmarsuren
Irkutsk State University, Irkutsk, Russia

Series: Materials Science and Technologies
BISAC: TEC021000

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Pd(β-diketonate)2/BF3∙OEt2 catalytic systems in “phosphine-free” and “phosphine-modified” fashions have been tested in the position isomerization of 1-hexene, dimerization of propylene, dimerization of styrene, telomerization of butadiene with diethylamine, addition polymerization of norbornene and its derivatives. For such systems exemplified by Pd(acac)2/BF3∙OEt2 and Pd(acac)2/PR3/BF3∙OEt2 general principles of the two-stage route of H(L)2-nPd(L’)nBF4 active sites formation are formulated, where L — unsaturated hydrocarbon, L’ — PR3 (R=Ph, n-Bu),n=0, 1, 2. This book presents an investigation into the application of BF3•OEt2 as multifunctional component of active in the transformation of unsaturated hydrocarbons Pd(II)- and Ni(0, I, II)-based catalyst systems. (Imprint: Novinka)

ABSTRACT

INTRODUCTION

1. FORMATION OF METAL COMPLEX CATALYSTS FOR THE OLIGOMERIZATION OF ALKENES ON THE BASE OF NICKEL IN DIVERSE OXIDATION STATES

2. FORMATION OF METAL COMPLEX CATALYSTS FOR THE TRANSFORMATION OF UNSATURATED SUBSTRATES ON THE BASE OF PD(Β-DIKETONATE)2 AND BF3∙OET2

ACKNOWLEDGEMENTS

REFERENCES

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